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Sheppy Adhesives ADH9 - SAFETY DATA SHEET 

SAFETY DATA SHEET ADH9 EVO-STIK 3019

1. IDENTIFICATION OF THE PREPARATION AND THE COMPANY

Product Name: 
EVO-STIK 3019
Product Code:
455919

Supplier: Sheppy Limited 

Rushenden Road

Queenborough

Kent 

ME11 5HH 

Telephone No: (01795) 580181

Fax No: (01795) 580649

2. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient Name 
 EC No.
CAS No.
Content 
Classification
Bisphenol A-Epichlorohydrin Epoxy Resin (Number AV MW<700) 500-033-5 25068-38-6  <1% Xi;R36/38. N,R51/53. R43
Butanone  201-159-0 78-93-3  60-100% F;R11 Xi;R36 R66 R67
Cyclohexanone  203-631-1  108-94-1 1-5% R10 Xn; R20
Ethanol  200-578-6  64-17-5 <1%  F;R11
Tetrahydrofuran  203-726-8 109-99-9 5-10% Xi; R36/37. F:R11. R19
(The full Text for All R-Phrases are Displayed in Section 16)

3. HAZARDS IDENTIFICATION

Highly flammable. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Irritating to eyes.
Vapours are heavier than air and can travel long distances to a source of ignition. Pilot lights can ignite the vapour.
CLASSIFICATION: Xi: R36. F;R11. R66. R67.

4. FIRST AID MEASURES

Inhalation: Remove victim immediately from source of exposure. Move the exposed person to fresh air at once. Get medical attention.
Ingestion: DO NOT induce vomiting. Get medical attention immediately.
Skin Contact: Promptly flush contaminated skin with water. Promptly remove clothing if soaked through and flush the skin with water. Wash skin with soap and water. Get medical attention if irritation perisists after washing.
Eye Contact: Rinse the eye with water immediately. Continue to rinse for at least 15 minutes and get medical attention..

5. FIRE FIGHTING MEASURES

Extinguishing Media: Fire can be extinguished using: Powder, Foam.
Unusal Fire & Explosion Hazards: Generates massive smoke during fire. Vapours are heavier than air and may spread near ground to sources of ignition. HIGHLY INFLAMMABLE! Risk of explosion in closed containers if pressure rises rapidly. Solvent vapours may form exlosive mixtures with air.
Specific Hazards: Toxic gases/vapours/fumes of Carbon dioxide (CO2). Carbon monoxide(CO).
Protective measure in fire: Wear self contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions: Avoid skin and eye contact. Ensure adequate ventilation. Wear personal protective equipment
Environmental precautions: Prevent entry into drains and water courses.
Spill Clean-Up Methods: Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Run-off or release to sewer, waterway or ground is forbidden. Absorb onto sand, earth or absorbent granules. Pick up with non-sparking tools and place into metal containers with seal able lids. Mark containers with details of hazards and store in designated area ready for disposal.

7. HANDLING AND STORAGE

Usages Precautions: Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level.
Storage Precautions: Flammable/combustible - Keep away from oxidisers, heat and flames. Ground container and transfer equipment to eliminate static electric sparks. Store at moderate temperature in dry, well ventilated area.
Storage Class: Flammable liquid storage.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Ingredient Name 
STD. 
LT - ppm
LT - mg/m3
ST ppm 
ST - mg/m3
Ethanol  WEL  1000 ppm 1920 mg/m3    
Butanone  WEL  200 ppm (Sk) 600 mg/m3 (Sk) 300 ppm (Sk)  899 mg/m3 (Sk)
Cyclohexanone  WEL  10 ppm (Sk)   20 ppm (Sk)  
Tetrahydrofuran  WEL  50 ppm(Sk)   100 ppm(Sk)  

Protective Equipment

Engineering Measures: Explosion-proof general and local exhaust ventilation.
Respiratory Equipment: Respiratory protection must be used if air contamination exceeds acceptable level. Wear mask supplied with gas cartridge suitable for organic substances.
Hand Protection: Protective gloves must be used if there is a risk of direct contact or splash. Use protective gloves made of Nitrile. Use thin cotton gloves inside the rubber gloves if allergy risk.
Eye Protection: Wear splash-proof eye goggles to prevent any possibility of eye contact.
Other Protection: Wear appropriate clothing to prevent repated or prolonged skin contact.
Hygiene Measures: DO NOT SMOKE IN WORK AREA! Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking and using the toilet. Use appropriate skin cream to prevent drying of skin.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Thixotropic Liquid
Colour: Colourless
Odour: Organic solvents.
Boiling Point (oC) 65 760 mm Hg Relative Density: 0.9 @ 20 oC
Flash Point (oC) minus 14CC (Closed cup)

10. STABILITY AND REACTIVITY

Stability: Avoid heat, sparks, flames.
Materials to avoid: Strong oxidising substances.
Hazardous Decomposition Products: Fire or high temperatures create: Toxic gase/vapours.fumes of Carbon Dioxide(CO2) and Carbon Monoxide (CO).

11. TOXICOLOGICAL INFORMATION

Inhalation: Drowsiness, dizziness, disorientation, vertigo. Gas or vapour may irritate respiratory system.
Ingestion: Pneumonia may be the result if vomited material containing solvents reaches the lungs.
Skin contact: Prolonged contact may cause dryness of the skin. May cause skin irritation/eczema.
Eye contact: Irritating to eyes. Irritation, burning, lachrymation, blurred vision after liquid splash.
Health warnings: Defats the skin. Prolonged or repeated exposure may cause severe irritation.
Medical considerations: Skin disorders and allergies.

12. ECOLOGICAL INFORMATION

Ecotoxicity: Not regarded as dangerous for the environment. However, contamination of the aquatic or terrestrial environments should be avoided.

13. DISPOSAL CONSIDERATION

General Information: This material is classified as special waste as defined by Special Waste Regulations 1996 and must be disposed of by an authorised contractor.
Disposal Methods: Dispose of waste and residues in accordance with local authority requirements. Do not allow runoff to sewer, waterway or ground. Recover and reclaim or recycle, if practical.
Waste Class: Classifed as Special Waste. Not permitted for landfill in liquid state.

14. TRANSPORT INFORMATION

UK ROAD CLASS PROPER SHIPPING NAME: ADHESIVES
UN NO. ROAD 1133  UK ROAD PACK GR.  III
ADR CLASS NO.  3 ADR CLASS Class 3: Flammable liquids
ADR PACK GROUP III  HAZARD NO. (ADR) 30
ADR LABEL NO.  3  HAZCHEM CODE  3Y
CEFIC TEC(R) NO.  30GF1-III,30GF1-sp RID CLASS NO. 3
RID PACK GROUP III  UN NO. SEA 1133
IMDG CLASS  3 EMS F-E, S-D
MFAG  See Guide  MARINE POLLUTANT  No.
UN NO. AIR  1133  AIR CLASS  3
AIR PACK GR. III    

15. REGULATORY INFORMATION

Label for Supply:

Irritant Highly

Flammable

Risk Phrases:  R11 Highly flammable
  R36  Irritating to eyes
R66  Repeated exposure may cause skin dryness or cracking
R67  Vapours may cause drowsiness and dizziness
Safety Phrases: S2  Keep out of the reach of children
  S9  Keep container in a well ventiliated place
S16  Keep away from sources of iginition - No smoking
S26  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S46  If swallowed, seek medical advice immediately and show this container or label.
S51  Use only in well-ventiliated areas.
S56  Dispose of this material and its container to hazardous or special waste collection point
P5  Contains expoxy constituents. See information supplied by the manufacturer.
P14  Contains Bisphenol A-Epichlorohydrin Epoxy Resin (Number AV MW<700). May produce an allergic reaction.

STATUTORY INSTRUMENTS

Chemicals (Hazard Information and Packaging) Regulations. Control of Substances Hazardous to Health.

APPROVED CODE OF PRACTICE

Classification and Labelling of Substances and Preparations Dangerous for Supply.

GUIDANCE NOTES

Workplace Exposure Limits EH40, CHIP for everyone HSG(108). Introduction to Local Exhaust Ventililation HS(G)37

16. OTHER INFORMATION

Information Sources: This safety data sheet was complied using current safety information supplied by distributor of raw materials.
Revision Comments: This safety data sheet supersedes all previous issues and users are cautioned to ensure that it is current. Destroy all previous data sheets and if in doubt contact Sheppy Limited.

Risk Phrases in Full:

R10 Flammable.
R11 Highly flammable.
R19 May form explosive peroxides.
R20 Harmful by inhalation.

R36 Irritating to eyes.
R36/37 Irritating to eyes and respiratory system.
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

REF: LEAFLET CHIPS/ADH9 ISSUE 1 -November 2005


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Address: Rushenden Road, Queenborough, Kent, ME11 5HH.
Tel: 01795 580181 Fax: 01795 580649 E-mail: sales@adhesives-sheppy.co.uk
Copyright © 2005 Sheppy Limited. All rights reserved. Revised: 13 March 2008
Created by Richard Stevens (Inetgraphics.co.uk)